Success! I managed to create the path effect myself. Attached (at the bottom of this post) you will find a ZIP file with the two files that need to be placed in the /Share/Extensions/ directory. Then, after Inkscape has been (re)started, "Inside Out" should appear in the "Modify Path" submenu (in the Extensions menu of Inkscape). Tested with versions 0.46 and 0.47pre0-1.
For anyone interested, I have created a small explanation of the steps that need to be taken, plus some tips.
A. The collection of paths that need to be turned inside out. In the dialog window, one can enter the point of origin, but I prefer to set that to (0,0) and move the paths to the left-top corner.
B. When the effect is applied, there might be things sticking out.
C. In fact, when you push the blue face to the background, you'll see that it is not very nice. This strange result is caused by the fact that all controlpoints are equal to the point itself and therefore, the lines remain straight and cross each other.
D. A very simple solution (to the problem under C) is to make sure that for each line segment, the two control points are set at about 1/3 and 2/3 of the segment.
E. Now, when the effect applied again, the control points are shifted further outwards
F. Again, we want push the blue face to the back, such that we can see the other faces
G. To finalize the transformation, we need to `plug a hole' in the blue face, manually. To do so, create a rectangle, and convert it to a path
H. Then, select both the blue face, and the red box, and select "Difference" from the "Path" menu.
I. Now, pull the four nodes outside and you are done!


