Hhm, I can't seem to reproduce your scenario where the bbox corner snaps to a grid line and not a grid intersection. Which options are selected in your snap control bar?
I guess the first thing is to make sure that only "Snap bbox corners" and "Snap to grid" are selected on the snap control bar.
Is that a raster image that you're trying to snap? If so, then it looks like you have a pixel grid?
Oh ok, I figured it out. Well at least I discovered one situation where this could happen. In my Document Properties, I have Snap to Grid set to Always Snap. That makes what I call a very strong snap. If I change it instead to "Snap when closer than" and make the distance 1 (which makes the weakest snap), AND I'm zoomed in far enough, I can make the bbox corner snap to a grid line. If I'm not zoomed in very much, it can't happen. So you may be able to avoid snapping to the grid line, by not being zoomed very much, and not have to change the settings in Doc Prop.
There may be some other situations where this could happen, I'm not sure. I haven't discovered any others, although I'm not the snapping expert

And there may be a snap distance where you can avoid it snapping to the grid line, and still not have it set to 'Always snap'. You'll just have to experiment.
Let us know if any of that solves the problem. There may be other or better solutions
